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Exemplo de Baixa via Web service utilizando o método ExecuteWithXmlParams:
<soapenv:Envelope xmlns:soapenv="http://schemas.xmlsoap.org/soap/envelope/" xmlns:tot="http://www.totvs.com/">
<soapenv:Header />
<soapenv:Body>
<tot:ExecuteWithXmlParams xmlns:tot="http://www.totvs.com/">
<tot:ProcessServerName>FinTBCBaixaDataProcess</tot:ProcessServerName>
<tot:strXmlParams><![CDATA[<?xml version="1.0" encoding="utf-8"?>
<FinTBCBaixaParamsProc xmlns="http://www.totvs.com.br/RM/" xmlns:i="http://www.w3.org/2001/XMLSchema-instance" xmlns:z="http://schemas.microsoft.com/2003/10/Serialization/">
<ActionModule xmlns="http://www.totvs.com/">F</ActionModule>
<ActionName xmlns="http://www.totvs.com/">FinTBCBaixaAction</ActionName>
<CanParallelize xmlns="http://www.totvs.com/">true</CanParallelize>
<CanSendMail xmlns="http://www.totvs.com/">false</CanSendMail>
<CanWaitSchedule xmlns="http://www.totvs.com/">false</CanWaitSchedule>
<CodUsuario xmlns="http://www.totvs.com/">mestre</CodUsuario>
<ConnectionId i:nil="true" xmlns="http://www.totvs.com/" />
<ConnectionString i:nil="true" xmlns="http://www.totvs.com/" />
<Context xmlns="http://www.totvs.com/" xmlns:a="http://www.totvs.com.br/RM/">
<a:_params xmlns:b="http://schemas.microsoft.com/2003/10/Serialization/Arrays">
<b:KeyValueOfanyTypeanyType>
<b:Key i:type="c:string" xmlns:c="http://www.w3.org/2001/XMLSchema">$CODCOLIGADA</b:Key>
<b:Value i:type="c:int" xmlns:c="http://www.w3.org/2001/XMLSchema">1</b:Value>
</b:KeyValueOfanyTypeanyType>
<b:KeyValueOfanyTypeanyType>
<b:Key i:type="c:string" xmlns:c="http://www.w3.org/2001/XMLSchema">$CODSISTEMA</b:Key>
<b:Value i:type="c:string" xmlns:c="http://www.w3.org/2001/XMLSchema">F</b:Value>
</b:KeyValueOfanyTypeanyType>
<b:KeyValueOfanyTypeanyType>
<b:Key i:type="c:string" xmlns:c="http://www.w3.org/2001/XMLSchema">$CODUSUARIO</b:Key>
<b:Value i:type="c:string" xmlns:c="http://www.w3.org/2001/XMLSchema">mestre</b:Value>
</b:KeyValueOfanyTypeanyType>
</a:_params>
<a:Environment>DotNet</a:Environment>
</Context>
<PrimaryKeyList xmlns:d2p1='http://schemas.microsoft.com/2003/10/Serialization/Arrays' xmlns='http://www.totvs.com/'>
<d2p1:ArrayOfanyType>
<d2p1:anyType xmlns:d4p1='http://www.w3.org/2001/XMLSchema' i:type='d4p1:short'>1</d2p1:anyType>
<d2p1:anyType xmlns:d4p1='http://www.w3.org/2001/XMLSchema' i:type='d4p1:int'>22752</d2p1:anyType>
</d2p1:ArrayOfanyType>
</PrimaryKeyList>
<PrimaryKeyNames xmlns:d2p1='http://schemas.microsoft.com/2003/10/Serialization/Arrays' xmlns='http://www.totvs.com/'>
<d2p1:string>CODCOLIGADA</d2p1:string>
<d2p1:string>IDLAN</d2p1:string>
</PrimaryKeyNames>
<CodColigada>1</CodColigada>
<CodMoeda>R$</CodMoeda>
<CodUsuario>mestre</CodUsuario>
<ContabilizarPosBaixa>false</ContabilizarPosBaixa>
<CotacaoBaixa>0</CotacaoBaixa>
<DataBaixa>2019-12-19</DataBaixa>
<Lancamentos>
<FinTBCBaixaLancamento>
<CodColigada>1</CodColigada>
<IdLan>22752</IdLan>
<Pagamentos>
<FinTBCBaixaPagamento>
<CodColCxa>1</CodColCxa>
<CodColigada>1</CodColigada>
<CodCxa>0004</CodCxa>
<Contabilizacao>
<FinTBCBaixaContabilizacao />
</Contabilizacao>
<IdFormaPagamento>1</IdFormaPagamento>
<IdPagto>1</IdPagto>
<Valor>100</Valor>
</FinTBCBaixaPagamento>
</Pagamentos>
<ValorDesconto>0</ValorDesconto>
<ValorJuros>0</ValorJuros>
<ValorMulta>0</ValorMulta>
</FinTBCBaixaLancamento>
</Lancamentos>
<TipoGeracaoExtratoBaixa>ExtratoParaCadaLancamento</TipoGeracaoExtratoBaixa>
<UsarDataDefaultBaixa>false</UsarDataDefaultBaixa>
<UsarDataVencimentoBaixa>false</UsarDataVencimentoBaixa>
</FinTBCBaixaParamsProc>]]></tot:strXmlParams>
</tot:ExecuteWithXmlParams>
</soapenv:Body>
</soapenv:Envelope>